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BRENDA KEGG MetaCyc

isoprenoid biosynthesis (BRENDA)

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EC Number Recommended Name Reaction BRENDA Pathway Name KEGG Pathway Name MetaCyc Pathway Name Reaction ID BRENDA Reaction ID KEGG Reaction ID MetaCyc Reaction ID SABIO-RK
show all sequences2.2.1.7 1-deoxy-D-xylulose-5-phosphate synthase pyruvate + D-glyceraldehyde 3-phosphate = 1-deoxy-D-xylulose 5-phosphate + CO2 isoprenoid biosynthesis Thiamine metabolism,
Terpenoid backbone biosynthesis,
Metabolic pathways,
Biosynthesis of secondary metabolites,
Biosynthesis of antibiotics
methylerythritol phosphate pathway I,
methylerythritol phosphate pathway II,
thiazole biosynthesis I (facultative anaerobic bacteria),
thiazole biosynthesis II (aerobic bacteria),
pyridoxal 5'-phosphate biosynthesis I
BR37092 show the reaction diagram,
BS260856 show the reaction diagram
R05636 show the reaction diagram DXS-RXN show the reaction diagram  
show all sequences2.5.1.85 all-trans-nonaprenyl diphosphate synthase [geranylgeranyl-diphosphate specific] geranylgeranyl diphosphate + 5 isopentenyl diphosphate = 5 diphosphate + all-trans-nonaprenyl diphosphate isoprenoid biosynthesis Terpenoid backbone biosynthesis,
Biosynthesis of secondary metabolites
nonaprenyl diphosphate biosynthesis II BR49315 show the reaction diagram R09251 show the reaction diagram RXN-11486 show the reaction diagram  
show all sequences2.5.1.89 tritrans,polycis-undecaprenyl-diphosphate synthase [geranylgeranyl-diphosphate specific] geranylgeranyl diphosphate + 7 isopentenyl diphosphate = 7 diphosphate + tritrans,heptacis-undecaprenyl diphosphate isoprenoid biosynthesis Terpenoid backbone biosynthesis   BR49320 show the reaction diagram R09730 show the reaction diagram RXN-11488 show the reaction diagram  
show all sequences2.5.1.1 dimethylallyltranstransferase geranyl diphosphate + isopentenyl diphosphate = diphosphate + (2E,6E)-farnesyl diphosphate isoprenoid biosynthesis Terpenoid backbone biosynthesis,
Metabolic pathways,
Biosynthesis of secondary metabolites,
Biosynthesis of antibiotics
stellatic acid biosynthesis,
methyl phomopsenoate biosynthesis,
trans, trans-farnesyl diphosphate biosynthesis,
all-trans-farnesol biosynthesis,
bisabolene biosynthesis (engineered)
BR47562 show the reaction diagram R02003 show the reaction diagram FPPSYN-RXN show the reaction diagram 2041
show all sequences2.5.1.10 (2E,6E)-farnesyl diphosphate synthase geranyl diphosphate + isopentenyl diphosphate = diphosphate + (2E,6E)-farnesyl diphosphate isoprenoid biosynthesis Terpenoid backbone biosynthesis,
Metabolic pathways,
Biosynthesis of secondary metabolites,
Biosynthesis of antibiotics
stellatic acid biosynthesis,
methyl phomopsenoate biosynthesis,
trans, trans-farnesyl diphosphate biosynthesis,
all-trans-farnesol biosynthesis,
bisabolene biosynthesis (engineered)
BR47562 show the reaction diagram R02003 show the reaction diagram FPPSYN-RXN show the reaction diagram 2041
show all sequences2.5.1.29 geranylgeranyl diphosphate synthase geranyl diphosphate + isopentenyl diphosphate = diphosphate + (2E,6E)-farnesyl diphosphate isoprenoid biosynthesis Terpenoid backbone biosynthesis,
Metabolic pathways,
Biosynthesis of secondary metabolites,
Biosynthesis of antibiotics
stellatic acid biosynthesis,
methyl phomopsenoate biosynthesis,
trans, trans-farnesyl diphosphate biosynthesis,
all-trans-farnesol biosynthesis,
bisabolene biosynthesis (engineered)
BR47562 show the reaction diagram R02003 show the reaction diagram FPPSYN-RXN show the reaction diagram 2041
show all sequences2.5.1.10 (2E,6E)-farnesyl diphosphate synthase farnesyl diphosphate + isopentenyl diphosphate = geranyl diphosphate + diphosphate isoprenoid biosynthesis     BS355468 show the reaction diagram      
show all sequences2.5.1.84 all-trans-nonaprenyl-diphosphate synthase [geranyl-diphosphate specific] geranyl diphosphate + 7 isopentenyl diphosphate = 7 diphosphate + all-trans-nonaprenyl diphosphate isoprenoid biosynthesis Terpenoid backbone biosynthesis,
Biosynthesis of secondary metabolites
nonaprenyl diphosphate biosynthesis I BR49314 show the reaction diagram R09250 show the reaction diagram TRANS-OCTAPRENYLTRANSTRANSFERASE-RXN show the reaction diagram  
show all sequences4.2.3.145 ophiobolin F synthase (2E,6E,10E,14E)-geranylfarnesyl diphosphate + H2O = ophiobolin F + diphosphate isoprenoid biosynthesis   ophiobolin F biosynthesis BR51059 show the reaction diagram R10762 show the reaction diagram RXN-15427 show the reaction diagram  
2.5.1.-   (2E,6E)-farnesyl diphosphate + isopentenyl diphosphate = diphosphate + geranylgeranyl diphosphate isoprenoid biosynthesis Terpenoid backbone biosynthesis,
Metabolic pathways,
Biosynthesis of secondary metabolites,
Biosynthesis of antibiotics
paspaline biosynthesis,
stellatic acid biosynthesis,
methyl phomopsenoate biosynthesis,
ophiobolin F biosynthesis,
fusicoccin A biosynthesis,
brassicicene C biosynthesis,
geranylgeranyl diphosphate biosynthesis,
plaunotol biosynthesis,
rubber biosynthesis
BR47565 show the reaction diagram,
BS406958 show the reaction diagram,
BS407552 show the reaction diagram
R02061 show the reaction diagram,
R05555 show the reaction diagram,
R05556 show the reaction diagram
FARNESYLTRANSTRANSFERASE-RXN show the reaction diagram,
RXN0-5180 show the reaction diagram
2078
show all sequences2.5.1.29 geranylgeranyl diphosphate synthase (2E,6E)-farnesyl diphosphate + isopentenyl diphosphate = diphosphate + geranylgeranyl diphosphate isoprenoid biosynthesis Terpenoid backbone biosynthesis,
Metabolic pathways,
Biosynthesis of secondary metabolites,
Biosynthesis of antibiotics
paspaline biosynthesis,
stellatic acid biosynthesis,
methyl phomopsenoate biosynthesis,
ophiobolin F biosynthesis,
fusicoccin A biosynthesis,
brassicicene C biosynthesis,
geranylgeranyl diphosphate biosynthesis,
plaunotol biosynthesis,
rubber biosynthesis
BR47565 show the reaction diagram,
BS406958 show the reaction diagram,
BS407552 show the reaction diagram
R02061 show the reaction diagram,
R05555 show the reaction diagram,
R05556 show the reaction diagram
FARNESYLTRANSTRANSFERASE-RXN show the reaction diagram,
RXN0-5180 show the reaction diagram
2078
show all sequences2.5.1.87 ditrans,polycis-polyprenyl diphosphate synthase [(2E,6E)-farnesyl diphosphate specific] (2E,6E)-farnesyl diphosphate + isopentenyl diphosphate = diphosphate + geranylgeranyl diphosphate isoprenoid biosynthesis Terpenoid backbone biosynthesis,
Metabolic pathways,
Biosynthesis of secondary metabolites,
Biosynthesis of antibiotics
paspaline biosynthesis,
stellatic acid biosynthesis,
methyl phomopsenoate biosynthesis,
ophiobolin F biosynthesis,
fusicoccin A biosynthesis,
brassicicene C biosynthesis,
geranylgeranyl diphosphate biosynthesis,
plaunotol biosynthesis,
rubber biosynthesis
BR47565 show the reaction diagram,
BS406958 show the reaction diagram,
BS407552 show the reaction diagram
R02061 show the reaction diagram,
R05555 show the reaction diagram,
R05556 show the reaction diagram
FARNESYLTRANSTRANSFERASE-RXN show the reaction diagram,
RXN0-5180 show the reaction diagram
2078
show all sequences2.5.1.88 trans,polycis-polyprenyl diphosphate synthase [(2Z,6E)-farnesyl diphosphate specific] (2E,6E)-farnesyl diphosphate + isopentenyl diphosphate = diphosphate + geranylgeranyl diphosphate isoprenoid biosynthesis Terpenoid backbone biosynthesis,
Metabolic pathways,
Biosynthesis of secondary metabolites,
Biosynthesis of antibiotics
paspaline biosynthesis,
stellatic acid biosynthesis,
methyl phomopsenoate biosynthesis,
ophiobolin F biosynthesis,
fusicoccin A biosynthesis,
brassicicene C biosynthesis,
geranylgeranyl diphosphate biosynthesis,
plaunotol biosynthesis,
rubber biosynthesis
BR47565 show the reaction diagram,
BS406958 show the reaction diagram,
BS407552 show the reaction diagram
R02061 show the reaction diagram,
R05555 show the reaction diagram,
R05556 show the reaction diagram
FARNESYLTRANSTRANSFERASE-RXN show the reaction diagram,
RXN0-5180 show the reaction diagram
2078
show all sequences2.5.1.30 heptaprenyl diphosphate synthase (2E,6E)-farnesyl diphosphate + 4 isopentenyl diphosphate = 4 diphosphate + all-trans-heptaprenyl diphosphate isoprenoid biosynthesis Terpenoid backbone biosynthesis,
Biosynthesis of secondary metabolites
heptaprenyl diphosphate biosynthesis BR47476 show the reaction diagram R09247 show the reaction diagram TRANS-HEXAPRENYLTRANSTRANSFERASE-RXN show the reaction diagram 13830
show all sequences2.5.1.B41 trifunctional (all-E)-isoprenyl diphospate synthase (2E,6E)-farnesyl diphosphate + 4 isopentenyl diphosphate = 4 diphosphate + all-trans-heptaprenyl diphosphate isoprenoid biosynthesis Terpenoid backbone biosynthesis,
Biosynthesis of secondary metabolites
heptaprenyl diphosphate biosynthesis BR47476 show the reaction diagram R09247 show the reaction diagram TRANS-HEXAPRENYLTRANSTRANSFERASE-RXN show the reaction diagram 13830
show all sequences2.5.1.91 all-trans-decaprenyl-diphosphate synthase (2E,6E)-farnesyl diphosphate + 7 isopentenyl diphosphate = 7 diphosphate + all-trans-decaprenyl diphosphate isoprenoid biosynthesis Terpenoid backbone biosynthesis,
Biosynthesis of secondary metabolites
all-trans-decaprenyl diphosphate biosynthesis,
ubiquinol-10 biosynthesis (eukaryotic)
BR49323 show the reaction diagram R09249 show the reaction diagram RXN-9106 show the reaction diagram  
show all sequences2.5.1.1 dimethylallyltranstransferase dimethylallyl diphosphate + isopentenyl diphosphate = diphosphate + geranyl diphosphate isoprenoid biosynthesis Terpenoid backbone biosynthesis,
Metabolic pathways,
Biosynthesis of secondary metabolites,
Biosynthesis of antibiotics
mono-trans, poly-cis decaprenyl phosphate biosynthesis,
(3R)-linalool biosynthesis,
stellatic acid biosynthesis,
trans, trans-farnesyl diphosphate biosynthesis,
all-trans-farnesol biosynthesis,
viridicatumtoxin biosynthesis,
ipsdienol biosynthesis,
bisabolene biosynthesis (engineered),
linalool biosynthesis I,
(3S)-linalool biosynthesis,
geranyl diphosphate biosynthesis
BR47563 show the reaction diagram R01658 show the reaction diagram GPPSYN-RXN show the reaction diagram 1793
show all sequences2.5.1.10 (2E,6E)-farnesyl diphosphate synthase dimethylallyl diphosphate + isopentenyl diphosphate = diphosphate + geranyl diphosphate isoprenoid biosynthesis Terpenoid backbone biosynthesis,
Metabolic pathways,
Biosynthesis of secondary metabolites,
Biosynthesis of antibiotics
mono-trans, poly-cis decaprenyl phosphate biosynthesis,
(3R)-linalool biosynthesis,
stellatic acid biosynthesis,
trans, trans-farnesyl diphosphate biosynthesis,
all-trans-farnesol biosynthesis,
viridicatumtoxin biosynthesis,
ipsdienol biosynthesis,
bisabolene biosynthesis (engineered),
linalool biosynthesis I,
(3S)-linalool biosynthesis,
geranyl diphosphate biosynthesis
BR47563 show the reaction diagram R01658 show the reaction diagram GPPSYN-RXN show the reaction diagram 1793
show all sequences2.5.1.29 geranylgeranyl diphosphate synthase dimethylallyl diphosphate + isopentenyl diphosphate = diphosphate + geranyl diphosphate isoprenoid biosynthesis Terpenoid backbone biosynthesis,
Metabolic pathways,
Biosynthesis of secondary metabolites,
Biosynthesis of antibiotics
mono-trans, poly-cis decaprenyl phosphate biosynthesis,
(3R)-linalool biosynthesis,
stellatic acid biosynthesis,
trans, trans-farnesyl diphosphate biosynthesis,
all-trans-farnesol biosynthesis,
viridicatumtoxin biosynthesis,
ipsdienol biosynthesis,
bisabolene biosynthesis (engineered),
linalool biosynthesis I,
(3S)-linalool biosynthesis,
geranyl diphosphate biosynthesis
BR47563 show the reaction diagram R01658 show the reaction diagram GPPSYN-RXN show the reaction diagram 1793
show all sequences2.7.7.60 2-C-methyl-D-erythritol 4-phosphate cytidylyltransferase CTP + 2-C-methyl-D-erythritol 4-phosphate = diphosphate + 4-(cytidine 5'-diphospho)-2-C-methyl-D-erythritol isoprenoid biosynthesis Terpenoid backbone biosynthesis,
Metabolic pathways,
Biosynthesis of secondary metabolites,
Biosynthesis of antibiotics
methylerythritol phosphate pathway I,
methylerythritol phosphate pathway II
BR36947 show the reaction diagram R05633 show the reaction diagram 2.7.7.60-RXN show the reaction diagram 5231
show all sequences2.5.1.81 geranylfarnesyl diphosphate synthase geranylgeranyl diphosphate + isopentenyl diphosphate = (2E,6E,10E,14E)-geranylfarnesyl diphosphate + diphosphate isoprenoid biosynthesis   stellatic acid biosynthesis,
ophiobolin F biosynthesis
BR48628 show the reaction diagram R07475 show the reaction diagram RXN-8813 show the reaction diagram  
show all sequences2.5.1.B41 trifunctional (all-E)-isoprenyl diphospate synthase geranylgeranyl diphosphate + isopentenyl diphosphate = (2E,6E,10E,14E)-geranylfarnesyl diphosphate + diphosphate isoprenoid biosynthesis   stellatic acid biosynthesis,
ophiobolin F biosynthesis
BR48628 show the reaction diagram R07475 show the reaction diagram RXN-8813 show the reaction diagram  
show all sequences1.1.1.1 alcohol dehydrogenase geraniol + NAD+ = geranial + NADH + H+ isoprenoid biosynthesis Geraniol degradation,
Biosynthesis of antibiotics
beta myrcene degradation,
geraniol and nerol degradation
BR50498 show the reaction diagram R10308 show the reaction diagram RXN-11968 show the reaction diagram 13273
show all sequences1.1.1.347 geraniol dehydrogenase (NAD+) geraniol + NAD+ = geranial + NADH + H+ isoprenoid biosynthesis Geraniol degradation,
Biosynthesis of antibiotics
beta myrcene degradation,
geraniol and nerol degradation
BR50498 show the reaction diagram R10308 show the reaction diagram RXN-11968 show the reaction diagram 13273
show all sequences2.5.1.32 15-cis-phytoene synthase 2 geranylgeranyl diphosphate = diphosphate + prephytoene diphosphate isoprenoid biosynthesis Carotenoid biosynthesis,
Metabolic pathways,
Biosynthesis of secondary metabolites
neurosporene biosynthesis,
trans-lycopene biosynthesis II (plants)
BR47500 show the reaction diagram R02065 show the reaction diagram 2.5.1.32-RXN show the reaction diagram 2081
show all sequences2.5.1.99 all-trans-phytoene synthase 2 geranylgeranyl diphosphate = diphosphate + prephytoene diphosphate isoprenoid biosynthesis Carotenoid biosynthesis,
Metabolic pathways,
Biosynthesis of secondary metabolites
neurosporene biosynthesis,
trans-lycopene biosynthesis II (plants)
BR47500 show the reaction diagram R02065 show the reaction diagram 2.5.1.32-RXN show the reaction diagram 2081
show all sequences3.1.7.11 geranyl diphosphate diphosphatase geranyl diphosphate + H2O = geraniol + diphosphate isoprenoid biosynthesis Monoterpenoid biosynthesis,
Metabolic pathways,
Biosynthesis of secondary metabolites,
Biosynthesis of antibiotics
geraniol and geranial biosynthesis,
secologanin and strictosidine biosynthesis
BR50059 show the reaction diagram R08396 show the reaction diagram RXN-17103 show the reaction diagram,
RXN-8618 show the reaction diagram
12967
show all sequences3.1.7.3 monoterpenyl-diphosphatase geranyl diphosphate + H2O = geraniol + diphosphate isoprenoid biosynthesis Monoterpenoid biosynthesis,
Metabolic pathways,
Biosynthesis of secondary metabolites,
Biosynthesis of antibiotics
geraniol and geranial biosynthesis,
secologanin and strictosidine biosynthesis
BR50059 show the reaction diagram R08396 show the reaction diagram RXN-17103 show the reaction diagram,
RXN-8618 show the reaction diagram
12967
show all sequences2.7.1.148 4-(cytidine 5'-diphospho)-2-C-methyl-D-erythritol kinase ATP + 4-(cytidine 5'-diphospho)-2-C-methyl-D-erythritol = ADP + 2-phospho-4-(cytidine 5'-diphospho)-2-C-methyl-D-erythritol isoprenoid biosynthesis Terpenoid backbone biosynthesis,
Metabolic pathways,
Biosynthesis of secondary metabolites,
Biosynthesis of antibiotics
methylerythritol phosphate pathway I,
methylerythritol phosphate pathway II
BR33803 show the reaction diagram R05634 show the reaction diagram 2.7.1.148-RXN show the reaction diagram  
show all sequences1.17.7.1 (E)-4-hydroxy-3-methylbut-2-enyl-diphosphate synthase (ferredoxin) 2-C-Methyl-D-erythritol 2,4-cyclodiphosphate + 2 Reduced ferredoxin <=> 1-Hydroxy-2-methyl-2-butenyl 4-diphosphate + H2O + 2 Oxidized ferredoxin isoprenoid biosynthesis Terpenoid backbone biosynthesis,
Metabolic pathways,
Biosynthesis of secondary metabolites,
Biosynthesis of antibiotics
methylerythritol phosphate pathway II   R08689 show the reaction diagram RXN0-882 show the reaction diagram  
show all sequences1.17.7.1 (E)-4-hydroxy-3-methylbut-2-enyl-diphosphate synthase (ferredoxin) (E)-4-hydroxy-3-methylbut-2-en-1-yl diphosphate + H2O + oxidized ferredoxin = 2-C-methyl-D-erythritol 2,4-cyclodiphosphate + reduced ferredoxin + 2 H+ isoprenoid biosynthesis     BR47612 show the reaction diagram      
show all sequences4.2.3.146 cyclooctat-9-en-7-ol synthase geranylgeranyl diphosphate + H2O = cyclooctat-9-en-7-ol + diphosphate isoprenoid biosynthesis   cyclooctatin biosynthesis BR51060 show the reaction diagram R10763 show the reaction diagram RXN-15429 show the reaction diagram  
show all sequences1.1.1.267 1-deoxy-D-xylulose-5-phosphate reductoisomerase 2-C-Methyl-D-erythritol 4-phosphate + NADP+ <=> 1-Deoxy-D-xylulose 5-phosphate + NADPH + H+ isoprenoid biosynthesis Terpenoid backbone biosynthesis,
Metabolic pathways,
Biosynthesis of secondary metabolites,
Biosynthesis of antibiotics
methylerythritol phosphate pathway I,
methylerythritol phosphate pathway II
BR29286 show the reaction diagram R05688 show the reaction diagram DXPREDISOM-RXN show the reaction diagram 5284
show all sequences1.3.1.83 geranylgeranyl diphosphate reductase phytyl diphosphate + 3 NADP+ = geranylgeranyl diphosphate + 3 NADPH + 3 H+ isoprenoid biosynthesis Terpenoid backbone biosynthesis,
Metabolic pathways,
Biosynthesis of secondary metabolites
  BR49043 show the reaction diagram R02063 show the reaction diagram RXN-10625 show the reaction diagram  
show all sequences2.5.1.B14 (2E,6E)-farnesyl-diphosphate all-trans-nonaprenyl diphosphate synthase (2E,6E)-farnesyl diphosphate + 6 isopentenyl diphosphate = 6 diphosphate + all-trans-nonaprenyl diphosphate isoprenoid biosynthesis     BR49316 show the reaction diagram      
show all sequences2.5.1.82 hexaprenyl diphosphate synthase [geranylgeranyl-diphosphate specific] geranylgeranyl diphosphate + 2 isopentenyl diphosphate = 2 diphosphate + all-trans-hexaprenyl diphosphate isoprenoid biosynthesis Terpenoid backbone biosynthesis,
Biosynthesis of secondary metabolites
  BR49312 show the reaction diagram R09246 show the reaction diagram RXN-11485 show the reaction diagram  
show all sequences2.5.1.B41 trifunctional (all-E)-isoprenyl diphospate synthase geranylgeranyl diphosphate + 2 isopentenyl diphosphate = 2 diphosphate + all-trans-hexaprenyl diphosphate isoprenoid biosynthesis Terpenoid backbone biosynthesis,
Biosynthesis of secondary metabolites
  BR49312 show the reaction diagram R09246 show the reaction diagram RXN-11485 show the reaction diagram  
show all sequences4.6.1.12 2-C-methyl-D-erythritol 2,4-cyclodiphosphate synthase 2-phospho-4-(cytidine 5'-diphospho)-2-C-methyl-D-erythritol = 2-C-methyl-D-erythritol 2,4-cyclodiphosphate + CMP isoprenoid biosynthesis Terpenoid backbone biosynthesis,
Metabolic pathways,
Biosynthesis of secondary metabolites,
Biosynthesis of antibiotics
methylerythritol phosphate pathway I,
methylerythritol phosphate pathway II
BR26153 show the reaction diagram R05637 show the reaction diagram RXN0-302 show the reaction diagram  
show all sequences2.7.1.216 farnesol kinase ATP + geranylgeraniol = ADP + geranylgeranyl phosphate isoprenoid biosynthesis     BR50486 show the reaction diagram   RXN-12325 show the reaction diagram  
show all sequences2.7.1.B19 geranylgeraniol kinase ATP + geranylgeraniol = ADP + geranylgeranyl phosphate isoprenoid biosynthesis     BR50486 show the reaction diagram   RXN-12325 show the reaction diagram  
show all sequences2.7.4.B4 geranylgeranyl phosphate kinase ATP + geranylgeranyl phosphate = ADP + geranylgeranyl diphosphate isoprenoid biosynthesis     BR50488 show the reaction diagram